TRANSITION-METAL-CATALYZED SYNTHESIS OF 7-MEMBERED CARBOCYCLIC RINGS

被引：29

作者：

DYKER, G

机构：

[1] FB6 - Organische Chemie, Universität-Gesamthochschule Duisburg, D-47048

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 20期

关键词：

CATALYSIS; CYCLOADDITIONS; DIELS-ALDER REACTIONS; RHODIUM COMPOUNDS; CARBOCYCLES;

D O I：

10.1002/anie.199522231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variant of the Diels‐Alder reaction with a vinylcyclopropane group as “homodiene” component enables a novel access to seven‐membered carbocyclic rings [Eq. (a)]. Metallacycles are considered as key intermediates of this rhodium‐catalyzed process. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：2223 / 2224

页数：2

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