INSERTION OF ALKENES INTO A PALLADIUM-ACETYL BOND

被引：89

作者：

OZAWA, F ^{[1
]}

HAYASHI, T ^{[1
]}

KOIDE, H ^{[1
]}

YAMAMOTO, A ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 20期

关键词：

D O I：

10.1039/c39910001469

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cationic acetylpalladium(II) complex cis-[Pd(COMe)(NCMe)(dppe)]+BF4- 2 exhibits extremely high reactivity toward simple alkenes including cyclopentene, cycloheptene and methyl acrylate to give the corresponding alkene-inserted complexes, which have been characterised by IR and NMR spectroscopy.

引用

页码：1469 / 1470

页数：2

共 18 条

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