ON THE SOLUBILITY OF AQUEOUS-ELECTROLYTES

被引：17

作者：

PERKYNS, J ^{[1
]}

PETTITT, BM ^{[1
]}

机构：

[1] UNIV HOUSTON,DEPT CHEM,HOUSTON,TX 77204

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 19期

关键词：

D O I：

10.1021/j100070a034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The existence of a high-density phase separation for molecular and continuum solvent models of ion-water solutions are demonstrated using the DRISM/HNC theory. The molecular lever effects which influence solubility and the inability of continuum models to exhibit some of these effects are discussed. The general trends in experimental alkali halide solubilities are found to be consistent with the present model calculations. The dependence of the phase separation on ion size is found to be primarily entropic in nature.

引用

收藏

页码：5147 / 5151

页数：5

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