SOLVENT INTERCALATION IN COBALT DIMETHYLGLYOXIMATO COMPLEXES - A MINIATURE HOST-GUEST SYSTEM

被引：6

作者：

ENGLERT, U

FISCHER, A

GAMMERSBACH, A

机构：

[1] Technische Hochschule Aachen, Institut für Anorganische Chemie, Aachen, D-52074

来源：

STRUCTURAL CHEMISTRY | 1995年 / 6卷 / 02期

关键词：

HOST-GUEST SYSTEM; SPACE FILLING; MOLECULAR PACKING; SOLVENT INTERCALATION; CRYSTAL ENVIRONMENT;

D O I：

10.1007/BF02281736

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When crystallized from appropriate solvents, the complex aqua-bis(dimethylglyoximato)nitrocobalt (III) may incorporate solvent molecules, thus forming a variety of mixed crystals. In the resulting host-guest crystals, the space group P2(1)/m and the packing motif of the pure host compound are retained. Lattice constants a and b remain essentially unaltered upon intercalation, whereas c and the monoclinic angle beta depend largely on the clathrated guest. Space filling and intermolecular contacts are discussed.

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页码：115 / 119

页数：5

相关论文

共 19 条

[1] SOLID-STATE SUPRAMOLECULAR ASSEMBLY VIA C-H...O HYDROGEN-BONDS - CRYSTAL-STRUCTURES OF THE COMPLEXES OF 1,3,5-TRINITROBENZENE WITH DIBENZYLIDENEACETONE AND 2,5-DIBENZYLIDENECYCLOPENTANONE [J].

BIRADHA, K ;

SHARMA, CVK ;

PANNEERSELVAM, K ;

SHIMONI, L ;

CARRELL, HL ;

ZACHARIAS, DE ;

DESIRAJU, GR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (19) :1473-1475

[2] STRUCTURAL STUDY OF COBALOXIME DERIVATIVES - MOLECULAR-STRUCTURE OF SODIUM SALT OF TRANS-DINITRO(DIMETHYLGLYOXIMATO)-(DIMETHYLGLYOXIME)COBALTATE(III) DIHYDRATE AND TRANS-NITROBIS(DIMETHYLGLYOXIMATO)-(TRIPHENYLPHOSPHINE)COBALT(III) [J].

BRESCIANIPAHOR, N ;

CALLIGARIS, M ;

RANDACCIO, L .

INORGANICA CHIMICA ACTA, 1978, 27 (01) :47-52

[3] PORPHYRIN SPONGES - CONSERVATION OF HOST STRUCTURE IN OVER 200 PORPHYRIN-BASED LATTICE CLATHRATES [J].

BYRN, MP ;

CURTIS, CJ ;

HSIOU, Y ;

KHAN, SI ;

SAWIN, PA ;

TENDICK, SK ;

TERZIS, A ;

STROUSE, CE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9480-9497

[4] TETRAARYLPORPHYRIN SPONGES - COMPOSITION, STRUCTURAL SYSTEMATICS, AND APPLICATIONS OF A LARGE CLASS OF PROGRAMMABLE LATTICE CLATHRATES [J].

BYRN, MP ;

CURTIS, CJ ;

KHAN, SI ;

SAWIN, PA ;

TSURUMI, R ;

STROUSE, CE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (05) :1865-1874

[5]

ENGLERT U, 1988, GAZZ CHIM ITAL, V118, P845

[6]

FRENZ BA, 1978, COMPUTING CRYSTALLOG

[7] THE CALCULATION OF MOLECULAR VOLUMES AND THE USE OF VOLUME ANALYSIS IN THE INVESTIGATION OF STRUCTURED MEDIA AND OF SOLID-STATE ORGANIC-REACTIVITY [J].

GAVEZZOTTI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) :5220-5225

[8]

KELLER E, 1988, SCHAKAL88 FORTRAN PR

[9] GUEST-DEPENDENT [CD(CN)2]N HOST STRUCTURES OF CADMIUM CYANIDE ALCOHOL CLATHRATES - 2 NEW [CD(CN)2]N FRAMEWORKS FORMED WITH PRNOH AND PRIOH GUESTS [J].

KIM, J ;

WHANG, D ;

LEE, JI ;

KIM, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1400-1402

[10]

Kitaigorodskii A.I., 1973, MOL CRYSTALS MOL