REACTIONS OF TETRAMESITYLDISILENE WITH AZIDES - SYNTHESIS OF DISILAAZIRIDINES

被引：24

作者：

GILLETTE, GR ^{[1
]}

WEST, R ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(90)87222-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of several organic azides (RN3) with tetramesityldisilene (1) were studied. Azides with R = Ph or Mes each gave two products, a disilaaziridine and a disilatriazoline. When R = PhCH2 or Me3SiCH2 intermediate adducts of the azide and the disilene were found. These adducts and the disilatriazolines both react thermally to yield the respective disilaaziridines. For R = Me3Si only a disilaaziridine was observed, the structure of which was determined by X-ray crystallography and was found to have a short SiSi internuclear distance of 2.23 Å. Crystal data: R = trimethylsilyl, a 23.561(3), b 19.001(3), c 16.916(3) Å, monoclinic, β = 106.095°, C2/c, Z = 8. Novel five-membered silicon heterocycles were isolated from the reactions of 1 with toluenesulfonyl azide and diphenylphosphonyl azide. © 1990.

引用

页码：45 / 55

页数：11

共 35 条

[11]

HUCHY J, 1982, ANGEW CHEM INT EDIT, V21, P301

[12]

Kaftory M., 1983, CHEM HALIDES PSEUDOH, P1254

[13]

KROSHEFSKY RD, 1975, INORG CHEM, V12, P3090

[14]

MARSMANN H, 1981, NMR BASIC PRINCIPLES, P130