A NOVEL CONSTRUCTION OF POLYFUNCTIONALIZED TRANS-HYDROINDANES VIA SULFUR-MEDIATED INTRAMOLECULAR DOUBLE MICHAEL TYPE REACTION

被引:15
作者
IHARA, M
SUZUKI, S
TANIGUCHI, N
FUKUMOTO, K
KABUTO, C
机构
[1] TOHOKU UNIV,INST PHARMACEUT,SENDAI,MIYAGI 980,JAPAN
[2] TOHOKU UNIV,FAC SCI,INSTRUMENTAL ANAL CTR CHEM,SENDAI,MIYAGI 980,JAPAN
关键词
D O I
10.1039/c39910001168
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
trans-Hydroindanes possessing an angular methyl group were stereoselectively synthesised via treatment of the four geometrical isomers 1a-1d of 9-methoxycarbonyl-4-methyl-1-phenylthionona-1,8-dien-3-one with tert-butyldimethylsilyl trifluoromethanesulphonate in the presence of triethylamine.
引用
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页码:1168 / 1169
页数:2
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