CHEMICAL CONFIRMATION FOR CONFIGURATIONS ASSIGNED TO INDOLE ALKALOIDS SPECIOGYNINE SPECIOCILIATINE MITRACILIATINE AND HIRSUTINE

被引：13

作者：

TRAGER, WF

PHILLIPSON, JD

BECKETT, AH

机构：

[1] Department of Pharmacy, Chelsea College of Science and Technology, University of London, Manresa Road, S

来源：

TETRAHEDRON | 1968年 / 24卷 / 06期

关键词：

D O I：

10.1016/S0040-4020(01)82542-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The faster rate of reaction with mercuric acetate of speciogynine compared with mitraciliatine, confirms the assignment of the normal configuration to speciogynine. The assigned configurations of speciociliatine (epiallo), mitraciliatine (pseudo) and hirsutine (pseudo) are confirmed by formation of these alkaloids from mitragynine (allo), speciogynine (normal) and dihydrocorynantheine (normal), respectively, by mercuric acetate oxidation followed by zinc/acetic acid reduction. © 1968.

引用

页码：2681 / +

页数：1

共 16 条

[11]

WEISBACH JA, 1965, TETRAHEDRON LETT, P3457

[12] THE REACTION OF RAUWOLFIA ALKALOIDS WITH MERCURIC ACETATE - CONVERSION OF 3-ISORESERPINE TO RESERPINE [J].