[(ETA(6)-C6H3ME3)RU(L-ALA)CL]

被引：29

作者：

CARTER, LC

DAVIES, DL

DUFFY, KT

FAWCETT, J

RUSSELL, DR

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194006220

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of (L-alaninato-N,O)chloro(eta6-1,3,5-trimethylbenzene)ruthenium(II), [RuCl(C3H6NO2)-(C9H12)], has been determined. The crystal contains two diastereoisomers having opposite chiralities at the metal centre. There is evidence of intermolecular hydrogen bonding between the amine protons of one diastereomer and the chloride of the other.

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页码：1559 / 1561

页数：3

相关论文

共 10 条

[1] THE ROLE OF TRANSITION-METAL ATOMS AS HYDROGEN-BOND ACCEPTORS - A NEUTRON-DIFFRACTION STUDY OF [NPRN4]2[PTCL4].CIS-[PTCL2(NH2ME)2] AT 20-K [J].

BRAMMER, L ;

CHARNOCK, JM ;

GOGGIN, PL ;

GOODFELLOW, RJ ;

ORPEN, AG ;

KOETZLE, TF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07) :1789-1798

[2] ARENE RUTHENIUM COMPLEXES WITH PICOLINIC-ACID, 1-AMINOETHYLPHOSPHONOUS ACID AND ALPHA-HYDROXYKETONES - X-RAY STRUCTURE OF [(ETA-1,3,5-C6ME3H3)RUCL(NC5H4CO2)] [J].

CARTER, L ;

DAVIES, DL ;

FAWCETT, J ;

RUSSELL, DR .

POLYHEDRON, 1993, 12 (13) :1599-1602

[3] THE REFINEMENT OF UNIT-CELL PARAMETERS FROM 2-CIRCLE DIFFRACTOMETER MEASUREMENTS [J].

CLEGG, W ;

SHELDRICK, GM .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1984, 167 (1-2) :23-27

[4] METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .53. CHIRAL HALF-SANDWICH COMPLEXES OF RHODIUM(III), IRIDIUM(III), IRIDIUM(I), AND RUTHENIUM(II) WITH ALPHA-AMINO-ACID ANIONS [J].

KRAMER, R ;

POLBORN, K ;

WANJEK, H ;

ZAHN, I ;

BECK, W .

CHEMISCHE BERICHTE, 1990, 123 (04) :767-778

[5]

Sheldrick G.M., 1986, SHELX86 PROGRAM SOLU

[6]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[7]

SHELDRICK GM, 1990, SHELXTLPC VERSION 4

[8] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF ETA-6-ARENE-RUTHENIUM(II) COMPLEXES OF ALANINE AND GUANINE DERIVATIVES [J].

SHELDRICK, WS ;

HEEB, S .

INORGANICA CHIMICA ACTA, 1990, 168 (01) :93-100

[9]

Sloan T. E., 1981, TOP STEREOCHEM, V12, P1

[10] DEMONSTRATION OF CONTROLLED ASYMMETRIC INDUCTION IN ORGANOIRON CHEMISTRY - SUGGESTIONS CONCERNING SPECIFICATION OF CHIRALITY IN PSEUDOTETRAHEDRAL METAL-COMPLEXES CONTAINING POLYHAPTO LIGANDS [J].

STANLEY, K ;

BAIRD, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (22) :6598-6599