ENANTIOSELECTIVE HYDROBORATIONS CATALYZED BY RHODIUM(+1) COMPLEXES

被引：58

作者：

BURGESS, K

VANDERDONK, WA

OHLMEYER, MJ

机构：

[1] Chemistry, Rice University, Houston, TX 77251

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86113-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-MeODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+1)/DIOP catalysts. Trends in the observed optical purities are discussed.

引用

页码：613 / 621

页数：9

共 19 条

[1] ZWITTERIONIC RHODIUM COMPLEXES AS CATALYSTS FOR THE HYDROFORMYLATION OF OLEFINS
AMER, I
ALPER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) : 3674 - 3676
[2] ELECTRON-SPIN-RESONANCE STUDIES OF RADICALS DERIVED FROM 1,3,2-BENZODIOXABOROLES
BABAN, JA
GOODCHILD, NJ
ROBERTS, BP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1986, (01): : 157 - 161
[3] DEVELOPMENT OF A SIMPLE GENERAL PROCEDURE FOR SYNTHESIS OF PURE ENANTIOMERS VIA CHIRAL ORGANOBORANES
BROWN, HC
SINGARAM, B
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (08) : 287 - 293
[4] BROWN HC, 1983, ASYMMETRIC SYNTHESIS
[5] CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES
BROWN, JM
LLOYDJONES, GC
[J]. TETRAHEDRON-ASYMMETRY, 1990, 1 (12) : 869 - 872
[6] REVERSAL OF CHIRALITY INDUCED BY ORTHO-METHOXYL SUBSTITUTION OF ARYLPHOSPHINE LIGANDS IN RHODIUM-CATALYZED ASYMMETRIC HYDROGENATION
BROWN, JM
MURRER, BA
[J]. TETRAHEDRON LETTERS, 1980, 21 (06) : 581 - 584
[7] ENANTIOSELECTIVE HYDROBORATION MEDIATED BY HOMOCHIRAL RHODIUM CATALYSTS
BURGESS, K
OHLMEYER, MJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (21) : 5178 - 5179
[8] ON DEUTERIUM-LABELING STUDIES FOR PROBING RHODIUM-CATALYZED HYDROBORATION REACTIONS
BURGESS, K
VANDERDONK, WA
KOOK, AM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (09) : 2949 - 2951
[9] NUCLEAR MAGNETIC-RESONANCE ENANTIOMER REAGENTS - CONFIGURATIONAL CORRELATIONS VIA NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS OF DIASTEREOMERIC MANDELATE, O-METHYLMANDELATE, AND ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETATE (MTPA) ESTERS
DALE, JA
MOSHER, HS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) : 512 - 519
[10] CATALYTIC ASYMMETRIC HYDROBORATION OF STYRENES
HAYASHI, T
MATSUMOTO, Y
ITO, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) : 3426 - 3428

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