METAL-METAL INTERACTIONS IN BINUCLEAR COMPLEXES EXHIBITING MIXED-VALENCY - MOLECULAR WIRES AND SWITCHES

被引：628

作者：

WARD, MD

机构：

来源：

CHEMICAL SOCIETY REVIEWS | 1995年 / 24卷 / 02期

关键词：

D O I：

10.1039/cs9952400121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Since the discovery of the Creutz-Taube ion, the study of mixed valency has been extended to a wide variety of metal fragments and bridging ligands. This review presents a survey of some recent developments in the area of mixed-valent complexes, from the areas of both coordination and organometallic chemistry, and then discusses mechanisms by which metal-metal interactions in such compounds may be reversibly controlled to provide prototypical 'molecular switches'.

引用

页码：121 / 134

页数：14

共 99 条

[1] MOLECULAR DESIGN IN ORGANOMETALLIC CHEMISTRY - THE FIRST EXAMPLE IN THE SYNTHESIS OF POLY(CYCLOPENTADIENYLIRON) CATIONS OF POLYAROMATIC ETHERS AND THIOETHERS
ABDELAZIZ, AS
DEDENUS, CR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) : 663 - 665
[2] MIXED-VALENCE IONS OF RUTHENIUM CONTAINING FUMARONITRILE AND TETRACYANOETHYLENE AS BRIDGING GROUPS
AMER, SI
DASGUPTA, TP
HENRY, PM
[J]. INORGANIC CHEMISTRY, 1983, 22 (14) : 1970 - 1975
[3] MAGNETIC SPIN-EXCHANGE INTERACTIONS BETWEEN SEVERAL METAL CENTERS IN PARAMAGNETIC-COMPLEXES WITH NEW POLYNUCLEATING BRIDGING LIGANDS
AMOROSO, AJ
MAHER, JP
MCCLEVERTY, JA
WARD, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (10) : 1273 - 1275
[4] AMOROSO AJ, UNPUB INORG CHEM
[5] SYNTHESIS AND 3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF A CONJUGATED PORPHYRIN POLYMER
ANDERSON, HL
MARTIN, SJ
BRADLEY, DDC
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (06): : 655 - 657
[6] CONJUGATED PORPHYRIN LADDERS
ANDERSON, HL
[J]. INORGANIC CHEMISTRY, 1994, 33 (05) : 972 - 981
[7] SUPEREXCHANGE METAL METAL COUPLING IN DINUCLEAR PENTAAMMINERUTHENIUM COMPLEXES INCORPORATING A 1,4-DICYANAMIDOBENZENE DIANION BRIDGING LIGAND
AQUINO, MAS
LEE, FL
GABE, EJ
BENSIMON, C
GREEDAN, JE
CRUTCHLEY, RJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) : 5130 - 5140
[8] BALZANI V, 1991, SUPRAMOLECULAR PHOTO
[9] STRUCTURAL AND SPECTROSCOPIC PROPERTIES OF [(RU(BIPY)2)2(MU-OR)2]2+ (R = ME OR ET, BIPY = 2,2'-BIPYRIDINE), A NEW CLASS OF STRONGLY INTERACTING BRIDGED BINUCLEAR RUTHENIUM COMPLEXES
BARDWELL, D
JEFFERY, JC
JOULIE, L
WARD, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (14): : 2255 - 2256
[10] RIGID ROD-LIKE DINUCLEAR RU(II) OS(II) TERPYRIDINE-TYPE COMPLEXES - ELECTROCHEMICAL-BEHAVIOR, ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTRONIC-ENERGY TRANSFER THROUGH PHENYLENE BRIDGES
BARIGELLETTI, F
FLAMIGNI, L
BALZANI, V
COLLIN, JP
SAUVAGE, JP
SOUR, A
CONSTABLE, EC
THOMPSON, AMWC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) : 7692 - 7699

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