METAL-METAL INTERACTIONS IN BINUCLEAR COMPLEXES EXHIBITING MIXED-VALENCY - MOLECULAR WIRES AND SWITCHES

被引：628

作者：

WARD, MD

机构：

来源：

CHEMICAL SOCIETY REVIEWS | 1995年 / 24卷 / 02期

关键词：

D O I：

10.1039/cs9952400121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Since the discovery of the Creutz-Taube ion, the study of mixed valency has been extended to a wide variety of metal fragments and bridging ligands. This review presents a survey of some recent developments in the area of mixed-valent complexes, from the areas of both coordination and organometallic chemistry, and then discusses mechanisms by which metal-metal interactions in such compounds may be reversibly controlled to provide prototypical 'molecular switches'.

引用

页码：121 / 134

页数：14

共 99 条

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