SYNTHETIC STUDIES ON INDOLE ALKALOIDS .6. SYNTHESIS OF TETRAHYDROAKUAMMICINE AND DIHYDROCORYNANTHEOL VIA 2-(3-INDOLYL)-4-PIPERIDONES

被引：21

作者：

DIEZ, A

VILA, C

SINIBALDI, ME

TROIN, Y

RUBIRALTA, M

机构：

[1] UNIV BARCELONA,FAC PHARM,ORGAN CHEM LAB,E-08028 BARCELONA,SPAIN

[2] UNIV CLERMONT FERRAND,CHIM SUBSTANCES NAT LAB,CNRS,URA 485,F-63177 CLERMONT FERRAND,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)61666-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of dihydrocorynantheol (5) and of the pentacyclic Strychnos alkaloid tetrahydroakuammicine (4) is reported from 5-ethyl-N-hydroxyethyl-2-(1-phenylsulfonyl-3-indolyl)-4-piperidineacetates (1) by means of a K(t)OBu/BF3.Et2O intramolecular cyclization.

引用

页码：733 / 736

页数：4

共 16 条

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