EQUILIBRIUM BETWEEN HOMOCUB-1(9)-ENE AND HOMOCUB-9-YLIDENE

被引：76

作者：

CHEN, N

JONES, M

WHITE, WR

PLATZ, MS

机构：

[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544

[2] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 13期

关键词：

D O I：

10.1021/ja00013a038

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of chemical trapping and laser flash photolysis experiments is used to demonstrate that homocub-9-ylidene and homocub-1(9)-ene are in equilibrium. The equilibrium constant can be shown to be close to unity at +20-degrees-C (0.23 less-than-or-equal-to K less-than-or-equal-to 4).

引用

页码：4981 / 4992

页数：12

共 59 条

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