A SKELETAL REARRANGEMENT STUDY OF LABELED BUTANES ON A SOLID SUPERACID CATALYST - SULFURIC-ACID TREATED ZIRCONIUM-OXIDE

被引：111

作者：

GARIN, F ^{[1
]}

SEYFRIED, L ^{[1
]}

GIRARD, P ^{[1
]}

MAIRE, G ^{[1
]}

ABDULSAMAD, A ^{[1
]}

SOMMER, J ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,FAC CHIM,PHYSICOCHIM HYDROCARBURES LAB,F-67008 STRASBOURG,FRANCE

来源：

JOURNAL OF CATALYSIS | 1995年 / 151卷 / 01期

关键词：

D O I：

10.1006/jcat.1995.1004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of n-butane and isobutane have been studied in a flow system in the presence of hydrogen at 250 degrees C using sulfuric acid treated zirconia as catalyst. The conversion of the butanes occurs with high selectivity in isomerization. The branched isomer reacts much faster than the linear one. The use of C-13 labelled starting material and analysis of the isotope distribution in the products show that the rearrangement is of intramolecular nature in accord with the superacidic properties of the catalyst. (C) 1995 Academic Press, Inc.

引用

页码：26 / 32

页数：7

共 33 条

[11] HINO M, 1984, REACT KINET CATAL LE, V25, P143
[12] HOFFMANN H, 1969, RECL TRAV CHIM PAY B, V88, P703
[13] THE NATURE OF ADSORBED CARBENIUM IONS AS ACTIVE INTERMEDIATES IN CATALYSIS BY SOLID ACIDS
KAZANSKY, VB
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (12) : 379 - 383
[14] NEW AND IMPROVED CATALYTIC PROCESSES FOR CLEAN FUELS
MAXWELL, IE
NABER, JE
[J]. CATALYSIS LETTERS, 1992, 12 (1-3) : 105 - 116
[15] REARRANGEMENT OF PENTACOORDINATED CARBONIUM-IONS OVER ZEOLITE-Y
MOTA, CJA
NOGUEIRA, L
KOVER, WB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (03) : 1121 - 1123
[16] HYDROGEN-DEUTERIUM EXCHANGE BETWEEN ZEOLITE-Y AND 3-METHYLPENTANE
MOTA, CJA
MARTINS, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) : 171 - 173
[17] OCINNEIDE A, 1975, J CATAL, V37, P311, DOI 10.1016/0021-9517(75)90165-7
[18] CARBOCATIONS AND ELECTROPHILIC REACTIONS
OLAH, GA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1973, 12 (03) : 173 - 212
[19] SUPERACIDIC FSO3H/HF CATALYZED BUTANE ISOMERIZATION .1.
OLAH, GA
FAROOQ, O
HUSAIN, A
NI, D
TRIVEDI, NJ
OLAH, JA
[J]. CATALYSIS LETTERS, 1991, 10 (3-4) : 239 - 247
[20] OLAH GA, 1992, J AM CHEM SOC, V115, P6985

← 1 2 3 4 →