ABOUT THE REVERSIBLE CONVERSION OF 3-DIETHYLAMINO-5-PHENYL-1,2,4-DITHIAZOLIUM-HALOMETALLATES INTO METAL-CHELATES OF 3-(THIO)BENZOYL(THIO)UREAS

被引：11

作者：

HARTUNG, J

ROSENBAUM, K

BEYER, L

LOSADA, J

FERNANDEZ, V

机构：

[1] UNIV AUTONOMA MADRID,FAC CIENCIAS,E-28049 MADRID,SPAIN

[2] ESCUELA SUPER INGN IND,DPTO INGN QUIM IND,E-28040 MADRID,SPAIN

来源：

JOURNAL FUR PRAKTISCHE CHEMIE | 1991年 / 333卷 / 04期

关键词：

D O I：

10.1002/prac.19913330404

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Redox reactions of 3-diethylamino-5-phenyl-1,2,4-dithiazolium halometallates 1a-e and metal chelates (M = CuII (2A), CoIII (2C), NiII (2F)) of 3-thiobenzoylthioureat was studied by cyclic voltammetry. 1 are converted by reduction into 2. The mechanism of the oxidation of 2A, C, F into 1a, d, e is dependent on the central ion. On formation of 1a from copper(II) chelates of 3-benzoylthiourea 3A by means of thionylchloride as well as by electrochemical oxidation 3-benzoylureas 4A are formed as sideproducts.

引用

页码：537 / 544

页数：8