DEVELOPMENT OF A CHIRAL STABILIZED AZOMETHINE YLID - A CHIRAL RELAY SYSTEM

被引：47

作者：

ANSLOW, AS

HARWOOD, LM

PHILLIPS, H

WATKIN, D

机构：

[1] UNIV OXFORD,DYSON PERRINS LAB,S PARKS RD,OXFORD OX1 3QY,ENGLAND

[2] UNIV OXFORD,CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(00)82350-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral, stabilised azomethine ylid (2) derived from (R)-2-phenylglycinol has been demonstrated to undergo enantioselective 1,3-dipolar cycloaddition reactions with a range of alkene and alkyne dipolarophiles.

引用

页码：169 / 172

页数：4

共 14 条

[11]

SCHOLLKOPF U, 1988, LIEBIGS ANN CHEM, P1025

[12]

SCHOLLKOPF U, 1981, SYNTHESIS-STUTTGART, P969

[13] AMINO-ACID APPROACH AS A GENERAL-ROUTE TO NONSTABILIZED AZOMETHINE YLIDES - FACILE GENERATION OF PARENT METHANIMINIUM METHYLIDE AND ITS 1-MONOSUBSTITUTED AND 1,1-DISUBSTITUTED DERIVATIVES [J].

TSUGE, O ;

KANEMASA, S ;

OHE, M ;

TAKENAKA, S .

CHEMISTRY LETTERS, 1986, (06) :973-976

[14] PI-FACIAL SELECTIVITY OF THE 1,3-DIPOLAR CYCLO-ADDITION OF THE PARENT AZOMETHINE YLIDE TO HOMOCHIRAL DIPOLAROPHILES [J].

WEE, AGH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (07) :1363-1364

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