MOLECULAR-STRUCTURE OF N-TRIMETHYLSILYLIMINO-TRIMETHYLPHOSPHORANE IN GAS-PHASE

被引：20

作者：

ASTRUP, EE ^{[1
]}

BOUZGA, AM ^{[1
]}

STARZEWSKI, KAO ^{[1
]}

机构：

[1] UNIV FRANKFURT,INST ANORGAN CHEM,D-6000 FRANKFURT,FED REP GER

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1979年 / 51卷 / 01期

关键词：

D O I：

10.1016/0022-2860(79)80268-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular structure of N-trimethylsilylimino-trimethylphosphorane has been investigated in the gas phase by the electron diffraction method. The PNSi skeleton is bent and the barrier to inversion is probably only about 10 kJ mole-1. The most important parameters are the following: ra(PN) = 1.542(5) Å, ra(SiN) = 1.705(5) Å, ra(PC) = 1.804(3) Å, ra(SiC) = 1.881(3) Å, ra(CH) = 1.086(4) Å, ∠ PNSi = 144.6(1.1)°, ∠ NPC = 115.7(1.1)°, ∠ NSiC = 110.7(0.4)°, δ C(3)PNSi = 29.8(9.4)°, δ C(6)SiNP = 30.3(10.6)°. © 1979.

引用

页码：51 / 59

页数：9

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