STUDIES ON FORSKOLIN RING-C FORMING REACTIONS

被引：20

作者：

JORDINE, G

BICK, S

MOLLER, U

WELZEL, P

DAUCHER, B

MAAS, G

机构：

[1] RUHR UNIV,FAK CHEM,D-44780 BOCHUM,GERMANY

[2] UNIV KAISERSLAUTERN,FACHBEREICH CHEM,D-67663 KAISERSLAUTERN,GERMANY

来源：

TETRAHEDRON | 1994年 / 50卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(01)80741-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Labdane derivative 27 has been prepared from (E,E)-farnesol (4). Selenium- and mercury-mediated cyclization of 24 leads to compounds with the opposite configuration at C-8 as found in forskolin.

引用

页码：139 / 160

页数：22

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