OLIGOSACCHARIDE CHARACTERIZATIONS BY FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY - FRAGMENTATION STUDY IN RELATION TO THE SUBSTITUENT AT THE REDUCING END

被引:14
作者
BOSSO, C
HEYRAUD, A
PATRON, L
机构
[1] Centre de Recherches sur les Macromoiécules Végétales (CERMAV-CNRS), Grenoble, 38041
来源
ORGANIC MASS SPECTROMETRY | 1991年 / 26卷 / 04期
关键词
D O I
10.1002/oms.1210260425
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A systematic investigation of oligosaccharides (cello-oligosaccharides, malto-oligosaccharides, their corresponding alditols and methylmaltosides) was undertaken using fast atom bombardment mass spectrometry. Experimental conditions were defined in order to obtain characteristic fragmentation in relation to the structure of the oligomers. The role of substituents at the reducing end in the fragmentation process was demonstrated.
引用
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页码:321 / 334
页数:14
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