SYNTHESIS AND CRYSTAL-STRUCTURE OF A RUTHENIUM COMPLEX CONTAINING 2 MONODENTATE DPPM LIGANDS (DPPM=BIS(DIPHENYLPHOSPHINO)METHANE)

被引：12

作者：

BARRAL, MC

JIMENEZAPARICIO, R

ROYER, EC

SAUCEDO, MJ

URBANOS, FA

GUTIERREZPUEBLA, E

RUIZVALERO, C

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM INORGAN,E-28040 MADRID,SPAIN

[2] CSIC,INST CIENCIAS MAT,E-28006 MADRID,SPAIN

[3] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,LAB RAYOS X,E-28040 MADRID,SPAIN

来源：

INORGANICA CHIMICA ACTA | 1993年 / 209卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)84989-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds trans-Ru(quin)2(dppm)2 and cis- and trans-Ru(quin)2(PPh3)2 (quin=2-quinaldinate anion; dppm=bis(diphenylphosphino)methane) have been prepared by the reaction of RuCl3.3H2O and Hquin, in basic alcoholic medium, in the presence of dppm and PPh3, respectively. The compounds are characterized by elemental analysis, IR, H-1 and P-31{H-1} NMR spectroscopy. The structure of trans-Ru(quin)2(dppm)2.2MeOH has been determined by X-ray crystallography. The compound has two bidentate N,O-quinaldinate and two monodentate dppm ligands in a trans-N, trans-O, trans-P arrangement.

引用

页码：105 / 109

页数：5

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