DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF ANNONIN-I, A BIOACTIVE NATURAL ACETOGENIN FROM ANNONA-SQUAMOSA

被引：19

作者：

GYPSER, A ^{[1
]}

BULOW, C ^{[1
]}

SCHARF, HD ^{[1
]}

机构：

[1] RHEIN WESTFAL TH AACHEN,INST ORGAN CHEM,D-52056 AACHEN,GERMANY

来源：

TETRAHEDRON | 1995年 / 51卷 / 07期

关键词：

D O I：

10.1016/0040-4020(94)01073-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The absolute configuration of annonin I 1, a bioactive natural acetogenin with a bis(tetrahydrofuran) moiety, containing eight chiral centres has been determined by analysis of its circular dichroism (CD). The Cotton effects of the natural appearing annonin I 1 have been compared with a reference substance 2 synthesized by a malonic ester synthesis.

引用

页码：1921 / 1930

页数：10

共 42 条

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