STUDIES IN RELATION TO BIOSYNTHESIS .48. PHOMAZARIN .2. C-13 NMR-SPECTRA AND BIOSYNTHESIS OF PHOMAZARIN

被引：12

作者：

BIRCH, AJ ^{[1
]}

SIMPSON, TJ ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA 2600,ACT,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 03期

关键词：

D O I：

10.1039/p19790000816

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 13C n.m.r. spectra of phomazarin methyl ester and seven further derivatives of phomazarin have been assigned. Incorporations of [ 13C]acetates and [13C]- and [14C]-malonates by cultures of Pyrenochaeta terrestris indicate that phomazarin is biosynthesised by condensation, followed by oxidative ring-fission, of a single nonaketide precursor chain.

引用

页码：816 / 822

页数：7

共 33 条

[11] NMR SPECTRAL STUDIES OF SOME QUINOLONE DERIVATIVES .3. C-13 MAGNETIC-RESONANCE SPECTRAL STUDIES OF 2-QUINOLONE AND 4-QUINOLONE DERIVATIVES [J].

CLARET, PA ;

OSBORNE, AG .

SPECTROSCOPY LETTERS, 1976, 9 (03) :167-175

[12]

ELSTNER EF, 1973, J BIOL CHEM, P5385

[13]

FUKIMOTO H, 1975, CHEM BER, V108, P1224

[14] SHIFTLESS RELAXATION REAGENT FOR C-13 MAGNETIC-RESONANCE OF ORGANOMETALLIC CARBONYL-COMPOUNDS [J].

GANSOW, OA ;

BURKE, AR ;

LAMAR, GN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (08) :456-&

[15]

GATENBECK S, 1969, Acta Chemica Scandinavica, V23, P3493, DOI 10.3891/acta.chem.scand.23-3493

[16] USE OF SINGLY AND DOUBLY LABELED ACETATE-C-13 IN ELUCIDATION OF STRUCTURES AND BIOSYNTHESIS OF MULTICOLIC AND MULTICOLOSIC ACIDS, NEW TETRONIC ACIDS FROM PENICILLIUM-MULTICOLOR [J].

GUDGEON, JA ;

HOLKER, JSE ;

SIMPSON, TJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (16) :636-638

[17] BIOSYNTHESIS OF METABOLITES OF PERICONIA-MACROSPINOSA FROM [1-C-13]-ACETATE, [2-C-13]-ACETATE, AND [1,2-C-13]-ACETATE [J].

HOLKER, JSE ;

YOUNG, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (13) :525-526

[18]

HOLKER JSE, 1975, TETRAHEDRON LETT, P4693

[19]

HOLKER JSE, 1974, JCS P1, P2134

[20]

HOWARD CC, 1974, JCS P1, P2240

← 1 2 3 4 →