ASYMMETRIC HETERO-DIELS-ALDER REACTIONS

被引：384

作者：

WALDMANN, H

机构：

[1] Institut for Organische Chemie, Universitat Karlsruhe, D-76128 Karlsruhe

来源：

SYNTHESIS-STUTTGART | 1994年 / 06期

关键词：

D O I：

10.1055/s-1994-25519

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric hetero Diels-Alder reactions provide a multitude of opportunities for the highly efficient regio- and stereoselective construction of various heterocycles in enantiomerically pure form. Despite the great potential of this synthetic methodology, its development was for a long time restricted to only a few efforts. However, during the last decade this field has been the subject of intense and successful activities. This review summarizes the progress which has been made in the development of efficient chiral auxiliary groups and catalysts for the steric steering of aza, oxa and thia Diels-Alder cycloadditions and thereby describes the current state of the art.

引用

页码：535 / 551

页数：17

共 124 条

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[Anonymous], 1993, ANGEW CHEM, DOI 10.1002/ange.19931050204

[2]

ARNOLD T, 1990, SYNLETT, P514

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