POLYPROPIONATE FRAGMENTS WITH 4 CONTIGUOUS CHIRAL CENTERS FROM ACETONE

被引：9

作者：

BIALECKI, M ^{[1
]}

VOGEL, P ^{[1
]}

机构：

[1] UNIV LAUSANNE,CHIM SECT,CH-1005 LAUSANNE,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 29期

关键词：

1,5-DIMETHYL-7-OXABICYCLO[2.2.1]HEPT-5-EN-2-YL; S(N)2' RING OPENING; (3RS,4SR,5SR,6SR)-4,6-DIBENZYLOXY-1,3,5-TRIMETHYLCYCLOHEXENE; (2RS,3SR,4RS,5RS)-3,5-DIBENZYLOXY-2,4-DIMETHYL-6-OXOHEPTONAL;

D O I：

10.1016/S0040-4039(00)77066-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder adduct of 2,4-dimethylfuran and 1-cyanovinyl acetate was converted with high stereoselectivity into 1,3,5-trimefilylcyclohexen-4,6-diol derivatives that can be cleaved into protected polypropionate fragments.

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页码：5213 / 5216

页数：4

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