THERMOLYSIS OF DICYCLOPENTADIENYLMETHYL ALCOHOLS - A NOVEL SYNTHESIS OF FULVENES

被引：1

作者：

KUMAGAI, T ^{[1
]}

OHNO, M ^{[1
]}

MITANI, K ^{[1
]}

YAMAMOTO, K ^{[1
]}

ODA, M ^{[1
]}

机构：

[1] OSAKA UNIV, FAC SCI, DEPT CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 01期

关键词：

D O I：

10.1246/bcsj.68.301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermolyses of isomeric mixtures of dicyclopentadienylmethyl alcohols were obtained by reactions of the corresponding isomeric mixture of metallodicyclopentadiene with aldehydes and ketones at 300 degrees C by a flow method. These thermolyses give by cycloreversion the corresponding isomeric mixtures of cyclopentadienyl-methyl alcohols. These mixtures in turn furnish the corresponding fulvenes upon treatment with bases. At higher temperatures, the thermolyses regenerate starting ketones, probably by retro-ene reaction of the cycloreversed alcohols.

引用

页码：301 / 304

页数：4

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