GROUND-STATE AND EXCITED-STATE PROPERTIES OF SOME LIGAND-BRIDGED RUTHENIUM(II) POLYPYRIDYL COMPLEXES WITH SPECTATOR-LIGAND-BASED EMISSION

被引：17

作者：

KALYANASUNDARAM, K

GRATZEL, M

NAZEERUDDIN, MK

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 02期

关键词：

D O I：

10.1039/dt9910000343

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From an examination of the absorption, luminescence and redox properties, the lowest excited state of the ligand-bridged polypyridyl complexes [{Ru(biq)2{2(dpp)]4+ and [(bipy)2Ru(dpp)Ru-(biq)2]4+ [dpp = 2,3-bis(2'-pyridyl)pyrazine, biq = 2,2'-biquinoline and bipy = 2,2'-bipyridine] is assigned to that of the charge-transfer type involving the spectator ligand biq.

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页码：343 / 346

页数：4

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