SYNTHESIS AND CRYSTAL-STRUCTURE OF A 4-COORDINATE ARYLOXO SAMARIUM COMPLEX [SM(OAR)(3)(THF)](THF) (OAR=2.6-DITERTBUTYL-4-METHYLPHENOXO)

被引：33

作者：

QI, GH

LIN, YG

HU, JY

SHEN, Q

机构：

[1] SUZHOU UNIV,DEPT CHEM,SUZHOU 215006,PEOPLES R CHINA

[2] ACAD SCI CHANGCHUN,CHANGCHUN INST APPL CHEM,SUZHOU 130022,PEOPLES R CHINA

来源：

POLYHEDRON | 1995年 / 14卷 / 03期

关键词：

D O I：

10.1016/0277-5387(94)00251-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aryloxo samarium complex [Sm(ArO)(3)(THF)](THF) has been prepared by the reaction of SmCl3 with 3 equiv. of NaOAr in THF. An X-ray crystallographic analysis shows the complex to be a four-coordinate aryloxide complex. Three oxygen atoms of aryloxo and one oxygen atom of THF coordinate to the samarium to form a distorted tetrahedron. The average Sm-O(Ar) distance is 2.151(7) Angstrom.

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页码：413 / 415

页数：3

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