STUDIES OF SOME COMPLEXES OF COPPER(2) HALIDES WITH ORGANIC DONORS

被引:11
作者
BARNES, JC
机构
[1] Chemistry Department, The University, Dundee
来源
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 01期
关键词
D O I
10.1016/0022-1902(69)80058-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complexes formed by the donors (D) 1·4 dioxan and tetrahydrofuran with CuCl2 and CuBr2 are characterised as (CuX2)3·2D and CuX2·2D. The thermal decomposition, heats of desolvation, hydration reactions and spectra of these compounds, and the acetonitrile adducts (CuX2)n·2AN (n = 2,3,5) are reported. The molecular structures of the dioxan and tetrahydrofuran adducts appear to be similar to those known for the acetonitrile and n.propanol adducts. © 1969.
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页码:95 / &
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