CHARACTERIZATION OF THE AIR-STABLE AND WATER-STABLE ORGANOMETALLIC RUTHENIUM(IV) COMPLEX [(ETA-3-ETA-2-ETA-3-C12H18)RUCL(H2O)][BF4]

被引:19
作者
STEED, JW [1 ]
TOCHER, DA [1 ]
机构
[1] UNIV LONDON UNIV COLL, DEPT CHEM, 20 GORDON ST, LONDON WC1H 0AJ, ENGLAND
关键词
D O I
10.1039/c39910001609
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of [(eta-3:eta-2-eta-3-C12H18)RuCl2] with Ag[BF4] (1:1 mole ratio) in water-acetone gives an air-stable aqueous solution of [(eta-3:eta-2:-eta-3-C12H18)RuCl(H2O)][BF4]; the isolated complex has been characterised by H-1 and C-13 NMR spectroscopy and X-ray crystallography.
引用
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页码:1609 / 1610
页数:2
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