CHARACTERIZATION OF THE AIR-STABLE AND WATER-STABLE ORGANOMETALLIC RUTHENIUM(IV) COMPLEX [(ETA-3-ETA-2-ETA-3-C12H18)RUCL(H2O)][BF4]

被引：19

作者：

STEED, JW ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL, DEPT CHEM, 20 GORDON ST, LONDON WC1H 0AJ, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 22期

关键词：

D O I：

10.1039/c39910001609

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [(eta-3:eta-2-eta-3-C12H18)RuCl2] with Ag[BF4] (1:1 mole ratio) in water-acetone gives an air-stable aqueous solution of [(eta-3:eta-2:-eta-3-C12H18)RuCl(H2O)][BF4]; the isolated complex has been characterised by H-1 and C-13 NMR spectroscopy and X-ray crystallography.

引用

页码：1609 / 1610

页数：2

共 13 条

[11] AQUEOUS ORGANOMETALLIC CHEMISTRY - SYNTHESIS AND STRUCTURE OF CHLORO[(1-3-ETA-6-8-ETA)-2,7-DIMETHYLOCTADIENEDIYL](SEMICARBAZIDE)-RUTHENIUM(IV) CHLORIDE DIHYDRATE [J].

SOMMERER, SO ;

PALENIK, GJ .

ORGANOMETALLICS, 1991, 10 (05) :1223-1224

[12] SYNTHESIS AND CHARACTERIZATION OF A PYRAZINE BRIDGED BIS-ALLYL RUTHENIUM(IV) COMPLEX - CRYSTAL-STRUCTURE OF [((ETA-3-ETA-3-C10H16)RUCL2)2(MU-C4H4N2)].2CHCL3 [J].

STEED, JW ;

TOCHER, DA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) :C34-C36

[13] BIS(ALLYL) RUTHENIUM(IV) COMPLEXES .1. SYNTHESIS OF COMPLEXES CONTAINING 4-MEMBERED RUTHENIUM HETEROCYCLES - CRYSTAL-STRUCTURE OF [RU(ETA-3-ETA-3-C-10 H-16)-(SNC7H4S-2)CL] [J].

TOERIEN, JG ;

VANROOYEN, PH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (06) :1563-1568

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