Process of Polarization and Analysis of the Water Adsorption on a Zeolite

被引:3
作者
Chabanis, G. [1 ]
Mouton, V. [1 ]
Abdoulaye, A. [1 ]
Giuntini, J. C. [1 ]
Zanchetta, J. V. [1 ]
Vanderschueren, J. [2 ]
机构
[1] Univ Montpellier 2, Lab Physicochim Mat Solides, Equipe Chim Phys, CNRS URA D0407, F-34095 Montpellier 5, France
[2] Inst Chim Sart Tilman, Lab Chim Macromol & Chim Phys, Grp Etud Polymeres Ind & Dosimetrie Appl, B-4000 Liege, Belgium
关键词
D O I
10.1007/BF02388678
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the study of the dielectric relaxation mechanisms in the zeolite Na-X, "Faujasite", by means of the method of Thermally Stimulated Depolarization Currents (TSDC), and polarization conductivity versus frequency. We give particular interest to the effect of adsorption on the evolution of dielectric parameters. Two distinct relaxation processes attributed to adsorbed water were found by TSDC measurements. Moreover, the polarization conductivity gives two sets of values of the potential barrier height The evolution of the polarization conductivity as a function of the rate p/p(o) is comparable to the curve showing the isothermal water adsorption.
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收藏
页码:177 / 182
页数:6
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