STRUCTURE AND DYNAMICS OF LANTHANIDE(III) COMPLEXES OF THE BIS(PROPYLAMIDE) OF DIETHYLENETRIAMINEPENTAACETIC ACID IN AQUEOUS-SOLUTION

被引:32
作者
GERALDES, CFGC [1 ]
URBANO, AM [1 ]
ALPOIM, MC [1 ]
HOEFNAGEL, MA [1 ]
PETERS, JA [1 ]
机构
[1] DELFT UNIV TECHNOL,ORGAN CHEM LAB,2628 BL DELFT,NETHERLANDS
关键词
D O I
10.1039/c39910000656
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
NMR shift and relaxation measurements show that the lanthanide(III) complexes of the bis(propylamide) of diethylenetriaminepentaacetic acid (H3L) occur in at least eight isomeric forms, in which the metal ion is coordinated by a water molecule and the octadentate chelated organic ligand.
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页码:656 / 658
页数:3
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