THE QUESTION OF DISPERSIVE KINETICS FOR THE INITIAL PHASE OF CHARGE SEPARATION IN BACTERIAL REACTION CENTERS

被引:62
作者
SMALL, GJ
HAYES, JM
SILBEY, RJ
机构
[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011
[2] MIT,DEPT CHEM,CAMBRIDGE,MA 02139
关键词
D O I
10.1021/j100198a005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, femtosecond time domain data have raised the possibility that the kinetics of the initial phase of charge separation could be dispersive due to the glasslike structural heterogeneity of proteins. Guided by spectral hole burning data, we have derived simple theoretical rate expressions which allow the question posed in the title to be explored.
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页码:7499 / 7501
页数:3
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