SHORT SYNTHETIC APPROACH TOWARDS THE TRIINDENOTRIPHENYLENE (HEMIFULLERENE) SYSTEM

被引：17

作者：

MEHTA, G

SHARMA, GVR

KUMAR, MAK

VEDAVYASA, TV

JEMMIS, ED

机构：

[1] School of Chemistry, University of Hyderabad

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 20期

关键词：

D O I：

10.1039/p19950002529

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A two-step synthesis of trimethyltribenzotriphenylene 2 from readily available starting materials involving three-fold Wittig reaction and three-fold oxidative photocyclization along a C-3-symmetry path is reported. Flash vacuum pyrolysis of 2 in the quest for the triindenotriphenylene (hemifullerene) system has so far led only to the formation of mono-coupled products 6 and 7.

引用

页码：2529 / 2530

页数：2

共 18 条

[1] LOCKING THE BOWL-SHAPED GEOMETRY OF CORANNULENE - CYCLOPENTACORANNULENE [J].