DIRECT CONVERSION OF ALCOHOLS INTO THIOLS

被引：74

作者：

NISHIO, T

机构：

[1] Department of Chemistry, University of Tsukuba, Tsukuba-shi

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 10期

关键词：

D O I：

10.1039/p19930001113

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple one-pot reaction between alcohols and 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide (Lawesson's reagent, LR) affords the corresponding thiols, accompanied by dehydration products, alkenes. Treatment of acyclic 1,4-diols with LR gives the 1,3-dienes. o-(Dihydroxymethyl)benzene derivatives yield the 1,3-dihydrobenzo[c]thiophenes when treated with LR.

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页码：1113 / 1117

页数：5

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