ELECTROLYTIC OXIDATION OF MOLTEN THIOCYANATE AND THE EFFECT OF LIGHT

被引：21

作者：

PUCCIARELLI, F

CESCON, P

HEYROVSKY, M

机构：

[1] UNIV DEGLI STUDI VENEZIA, IST CHIM GEN & INORGAN, I-30123 Venice, ITALY

[2] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CS-11840 PRAGUE, CZECHOSLOVAKIA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1979年 / 126卷 / 06期

关键词：

anode; electrolyte; photoconductivity;

D O I：

10.1149/1.2129204

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

On the basis of a study of the effect of light on an anode it is suggested that electrolytic oxidation of the SCN-ion in molten thiocyanates proceeds in two ways according to experimental conditions: The primarily formed thiocyanate radicals either polymerize to chemically stable parathiocyanogen (SCN)x, or they interact with anions of the melt forming trithiocyanate ion (SCN)3- which is oxidized to polytrithiocyanogen [(SCN)3]x, a chemically unstable species showing semiconductor photoresponse to light. © 1979, The Electrochemical Society, Inc. All rights reserved.

引用

页码：972 / 981

页数：10

共 35 条

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