REGIOSELECTIVE RING-OPENING OF A PALLADIUM(IV) ALKYLAROMATIC METALLACYCLE BY BENZYL GROUP MIGRATION FROM PALLADIUM TO THE AROMATIC CARBON AND X-RAY STRUCTURE OF THE RESULTING PALLADIUM(II) COMPLEX

被引:82
作者
BOCELLI, G
CATELLANI, M
GHELLI, S
机构
[1] UNIV PARMA,IST CHIM ORGAN,V DELLE SCI,I-43100 PARMA,ITALY
[2] CNR,CTR STRUTTURIST DIFFRATTOMETR,I-43100 PARMA,ITALY
[3] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY
关键词
D O I
10.1016/0022-328X(93)80486-U
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The stereochemical course of a Pd(II) --> Pd(IV) --> Pd(II) transformation is described for the first time through isolation of organometallic species containing the entire carbon skeleton.
引用
收藏
页码:C12 / C15
页数:4
相关论文
共 30 条
[1]  
AYE KT, 1989, ORGANOMETALLICS, V8, P1518
[2]  
BRATERMAN PS, 1986, REACTIONS COORDINATE, V1, P60
[3]   CONVENIENT SYNTHETIC ROUTES TO MEDPII, ME2PDII, AND ME3PDIV COMPLEXES - THE CRYSTAL-STRUCTURE OF THE MEDPDII COMPLEX [MEPD(2,2'-BIPYRIDYL)(GAMMA-PICOLINE)]BF4 [J].
BYERS, PK ;
CANTY, AJ ;
SKELTON, BW ;
WHITE, AH .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 336 (03) :C55-C60
[4]   THE OXIDATIVE ADDITION OF IODOMETHANE TO [PDME2(2,2'-BIPYRIDYL)] AND THE X-RAY STRUCTURE OF THE ORGANOPALLADIUM(IV) PRODUCT FAC-[PDME3(2,2'-BIPYRIDYL)L] [J].
BYERS, PK ;
CANTY, AJ ;
SKELTON, BW ;
WHITE, AH .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) :1722-1724
[5]   SYNTHESIS AND STUDY OF THE BENZYLPALLADIUM(IV) AND NAPHTHYLPALLADIUM(IV) COMPLEXES PDBRME2(CH2AR) (BPY2), PDBRME2(CH2AR) (PHEN2) AND MU-HYDROCARBYL PALLADIUM(IV)-PALLADIUM(IV) AND PALLADIUM(IV) PLATINUM(IV) COMPLEXES AND THE STRUCTURE OF FAC-PDBRME2(CH2-P-C6H4BR) (PHEN) [J].
BYERS, PK ;
CANTY, AJ ;
SKELTON, BW ;
TRAILL, PR ;
WATSON, AA ;
WHITE, AH .
ORGANOMETALLICS, 1990, 9 (12) :3080-3085
[6]   REACTIVITY AND MECHANISM IN OXIDATIVE ADDITION TO PALLADIUM(II) AND REDUCTIVE ELIMINATION FROM PALLADIUM(IV) AND AN ESTIMATE OF THE PALLADIUM-METHYL BOND-ENERGY [J].
BYERS, PK ;
CANTY, AJ ;
CRESPO, M ;
PUDDEPHATT, RJ ;
SCOTT, JD .
ORGANOMETALLICS, 1988, 7 (06) :1363-1367
[7]   SYNTHESIS OF THE 1ST ORGANOPALLADIUM(IV) CATIONS, INCLUDING THE 1ST X-RAY STUDY OF ISOSTRUCTURAL ORGANOPALLADIUM(IV) AND PLATINUM(IV) COMPLEXES, [FAC-MME3(TRIS(PYRAZOL-1-YL)METHANE-N,N',N'')]I [J].
BYERS, PK ;
CANTY, AJ ;
SKELTON, BW ;
WHITE, AH .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) :1093-1095
[8]   DEVELOPMENT OF ORGANOPALLADIUM(IV) CHEMISTRY - FUNDAMENTAL-ASPECTS AND SYSTEMS FOR STUDIES OF MECHANISM IN ORGANOMETALLIC CHEMISTRY AND CATALYSIS [J].
CANTY, AJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (02) :83-90
[9]   PALLADIUM-(II) AND PALLADIUM-(IV) COMPLEXES AS INTERMEDIATES IN CATALYTIC C-C BOND-FORMING REACTIONS [J].
CATELLANI, M ;
CHIUSOLI, GP .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 346 (01) :C27-C30
[10]   CONFORMATIONAL EFFECTS IN ELEMENTARY STEPS IN CATALYTIC REACTIONS - OXIDATIVE ADDITION OF 3-BROMOPROP-1-ENE TO A PALLADIUM(II) METALLACYCLIC COMPLEX [J].
CATELLANI, M ;
MANN, BE .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (02) :251-255