A DIVERGENT ROUTE FOR A TOTAL SYNTHESIS OF CYCLOPHELLITOL AND EPICYCLOPHELLITOL FROM A [2.2.2]OXABICYCLIC GLYCOSIDE PREPARED FROM D-GLUCAL

被引：42

作者：

MCDEVITT, RE ^{[1
]}

FRASERREID, B ^{[1
]}

机构：

[1] DUKE UNIV,DEPT CHEM,PAUL M GROSS CHEM LAB,DURHAM,NC 27708

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 12期

关键词：

D O I：

10.1021/jo00091a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.

引用

页码：3250 / 3252

页数：3

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