NOVEL TELLURIUM-CONTAINING P-TERPHENOQUINONE ANALOGS - PREPARATION AND UNIQUE REDOX PROPERTIES OF PARAMAGNETIC TELLURIUM-CENTERED RADICAL-CATION COMPLEXES

被引：7

作者：

TAMURA, R

NAGATA, Y

SHIMIZU, H

MATSUMOTO, A

ONO, N

KAMIMURA, A

HORI, K

机构：

[1] EHIME UNIV,FAC SCI,DEPT CHEM,MATSUYAMA,EHIME 790,JAPAN

[2] YAMAGUCHI UNIV,FAC LIBERAL ARTS,DEPT CHEM,YAMAGUCHI 753,JAPAN

来源：

ADVANCED MATERIALS | 1993年 / 5卷 / 10期

关键词：

D O I：

10.1002/adma.19930051005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amphoteric tellurium‐containing π‐donors'acceptors are reported. The electrical and magnetic properties of the charge‐transfer complexes and radical cation salts prepared from 1 (see Figure; X  Te, R1  Me) are presented. 1 exhibits a remarkably low oxidation potential compared with S analogues and a one‐step two‐electron reduction potential, indicating that its derivatives could also be of use as the first Te‐containing organic electron acceptors. (Figure Presented.) Copyright © 1993 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：719 / 721

页数：3

共 18 条

[1] SYNTHESIS AND STRUCTURE OF THE 1ST TELLURIUM(III) RADICAL CATION [J].

BJORGVINSSON, M ;

HEINZE, T ;

ROESKY, HW ;

PAUER, F ;

STALKE, D ;

SHELDRICK, GM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (12) :1677-1678

[2] RECENT PROGRESS ON CONDUCTING ORGANIC CHARGE-TRANSFER SALTS [J].

BRYCE, MR .

CHEMICAL SOCIETY REVIEWS, 1991, 20 (03) :355-390

[3]

COWAN D, 1987, CHEM ORGANIC SELENIU, V2, P463

[4] ORGANIC METALS CONTAINING TELLURIUM [J].

COWAN, DO ;

MCCULLOUGH, R ;

BAILEY, A ;

LERSTRUP, K ;

TALHAM, D ;

HERR, D ;

MAYS, M .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 67 (1-4) :277-294

[5] AN ELECTRON-SPIN-RESONANCE STUDY OF THE 2,5-DIPHENYLCHALCOPHENE RADICAL IONS [J].

DAVIES, AG ;

SCHIESSER, CH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 389 (03) :301-313

[6] TELLURIUM-CENTERED RADICAL CATIONS .1. THE 1,3-DITELLUROLE RADICAL CATION BY CHEMICAL, ELECTROCHEMICAL, AND PHOTOCHEMICAL OXIDATION [J].

DETTY, MR ;

HALEY, NF ;

EACHUS, RS ;

HASSETT, JW ;

LUSS, HR ;

MASON, MG ;

MCKELVEY, JM ;

WERNBERG, AA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (22) :6298-6304

[7]

ERIK E, 1992, TETRAHEDRON, V48, P9577

[8] TELLUROPHEN AND SOME OF ITS DERIVATIVES [J].

FRINGUELLI, F ;

TATICCHI, A .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (02) :199-+

[9]

HAY PJ, 1985, J CHEM PHYS, V82, P270, DOI 10.1063/1.448799

[10]

HAY PJ, 1985, J CHEM PHYS, V82, P299, DOI [10.1063/1.448975, 10.1063/1.448799, 10.1063/1.448800]

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