A NEW NMR METHOD FOR MEASURING THE LOCAL CORRELATION TIMES OF MOLECULES IN THE LIQUID-STATE

被引：5

作者：

DESVAUX, H ^{[1
]}

GOLDMAN, M ^{[1
]}

机构：

[1] CTR ETUD SACLAY,SERV PHYS ETAT CONDENSE,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1994年 / 91卷 / 06期

关键词：

D O I：

10.1051/jcp/1994910653

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The steady-state magnetizations of homonuclear spins experiencing a strong off-resonance irradiation are aligned with the effective field. Their amplitude is a function of the correlation time and of the angle between the static field and the effective field in the rotating frame. By varying the latter, one can determine the effective local correlation time or test large departure from isotropic Brownian rotation. Experimental illustrations are given.

引用

页码：653 / 659

页数：7

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