PROPERTIES OF COPPER ALUMINA SORBENTS USED FOR THE REMOVAL OF SULFUR-DIOXIDE

被引：40

作者：

POLLACK, SS

CHISHOLM, WP

OBERMYER, RT

HEDGES, SW

RAMANATHAN, M

MONTANO, PA

机构：

[1] US DOE,MORGANTOWN ENERGY TECHNOL CTR,MORGANTOWN,WV 26505

[2] PENN STATE UNIV,DEPT PHYS,MCKEESPORT,PA 15132

[3] W VIRGINIA UNIV,DEPT PHYS,MORGANTOWN,WV 26506

[4] CUNY BROOKLYN COLL,DEPT PHYS,BROOKLYN,NY 11210

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1988年 / 27卷 / 12期

关键词：

Copper Alumina Sorbents;

D O I：

10.1021/ie00084a013

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

An attempt has been made to determine the structure of Cu/alumina sorbents used for the removal of SO2 from flue gas. Fresh, used, and regenerated Grace η-alumina 1/16-in. spheres containing 7.2% Cu were studied by various techniques. X-ray and electron diffraction showed that the copper compounds are not crystalline. The magnetic susceptibilities were much higher than those of any of the copper compounds that might be expected in these sorbents. Extended X-ray absorption fine-structure analysis indicated that the copper is surrounded by an average of 2.4-2.7 oxygens and that the CuO units are very small or amorphous. The low coordination number may be related to the material being a good sorbent for SO2.

引用

页码：2276 / 2282

页数：7