THE MECHANISM OF THE ADDITION OF HALOALKANES TO ALKENES IN THE PRESENCE OF [RUH3(SIME2PH)(PPH3)3] AND [RUH2(PPH3)4]

被引:10
作者
DAVIS, R [1 ]
FURZE, JD [1 ]
COLEHAMILTON, DJ [1 ]
POGORZELEC, P [1 ]
机构
[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9AJ,SCOTLAND
关键词
D O I
10.1016/0022-328X(92)83495-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Kinetic and other studies have demonstrated that the addition of haloalkanes to alkenes in the presence of either [RuH3(SiMe2Ph)(PPh3)3] or [RuH2(PPh3)4] has a mechanism very similar to that observed in the presence of [RuCl2(PPh3)3]. The previous report of enhanced catalytic activity for the two hydrides has not been confirmed.
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页码:191 / 196
页数:6
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