THE MECHANISM OF THE ADDITION OF HALOALKANES TO ALKENES IN THE PRESENCE OF [RUH3(SIME2PH)(PPH3)3] AND [RUH2(PPH3)4]

被引：10

作者：

DAVIS, R ^{[1
]}

FURZE, JD ^{[1
]}

COLEHAMILTON, DJ ^{[1
]}

POGORZELEC, P ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9AJ,SCOTLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 440卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(92)83495-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Kinetic and other studies have demonstrated that the addition of haloalkanes to alkenes in the presence of either [RuH3(SiMe2Ph)(PPh3)3] or [RuH2(PPh3)4] has a mechanism very similar to that observed in the presence of [RuCl2(PPh3)3]. The previous report of enhanced catalytic activity for the two hydrides has not been confirmed.

引用

页码：191 / 196

页数：6

共 15 条

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