METAL ION INDUCED AQUATIONS .I. KINETICS OF HOMOGENEOUS REACTION OF IODOPENTAMMINECOBALT(3) PERCHLORATE WITH SILVER IONS

被引：13

作者：

LALOR, GC

RUSTAD, DS

机构：

[1] Chemistry Department, University of the West Indies, Mona

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 10期

关键词：

D O I：

10.1016/0022-1902(69)80108-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of the silver ion induced aquation of iodopentamminecobalt(III) perchlorate was studied at 44·9°C in the range of ionic strengths 4·9 × 10-2 M-8·06 × 10-2 M. The reaction proceeds by homogeneous and heterogeneous pathways. The rate constant for the former is given by the expression kobs = ka + k1 [Ag+]0 + k2 [Ag+]02, where ka the spontaneous" rate constant is 1·12 × 10-4 sec-1. The values of k1 and k2 at zero ionic strength are 0·8 M-1sec-1 and 1·8 × 102 M-2sec-1 respectively. © 1969."

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页码：3219 / &

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