(ORGANOARSONATO)POLYOXOVANADIUM CLUSTERS - PROPERTIES AND STRUCTURES OF THE VV CLUSTER [V10O24(O3ASC6H4-4-NH2)3]4- AND THE VIV/VV CLUSTER [H2(V6O10(O3ASC6H5)6)]2-

被引：42

作者：

KHAN, MI

CHANG, Y

CHEN, O

HOPE, H

PARKING, S

GOSHORN, DP

ZUBIETA, J

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

[2] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

[3] EXXON RES & DEV CO,ANNANDALE,NJ 08801

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 09期

关键词：

D O I：

10.1002/anie.199211971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three {V3O13} units linked to form a ring that encloses the central V atom are found in the V(V) title compound. The V(IV)/V(V) cluster consists of a layered structure composed of three {V2As2O4} rings. These are further examples of the exotic structures which are par for polyoxometalates. They show the profound influence that even a subtle change in the organic ligand can exert on the structure. The structure of the V(V) compound is shown on the right. . = V.

引用

页码：1197 / 1200

页数：4

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