IR SPECTROSCOPIC STUDY OF THE SKELETAL ISOMERIZATION OF BUTENE BY ALUMINA-SUPPORTED TUNGSTEN-OXIDE CATALYSTS

被引：54

作者：

MEIJERS, S ^{[1
]}

GIELGENS, LH ^{[1
]}

PONEC, V ^{[1
]}

机构：

[1] LEIDEN UNIV,LEIDEN INST CHEM,GORLAEUS LABS,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF CATALYSIS | 1995年 / 156卷 / 01期

关键词：

D O I：

10.1006/jcat.1995.1240

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface properties of supported tungsten oxide catalysts, pure tungsten oxide, and pure alumina were studied by IR spectroscopy, using pyridine and carbon monoxide as probes. The interaction of these catalysts with n-butenes, molecules which are isomerised selectively by the catalysts to isobutene, has also been studied by IR spectroscopy. A correlation is found between the catalytic properties of the catalysts and the strength and nature of the acidic sites found on their surface. (C) 1995 Academic Press, Inc.

引用

页码：147 / 153

页数：7

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