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THERMODYNAMICS OF LIQUID ALLOYS - EXPERIMENTAL-TECHNIQUES AND RESULTS

被引：44
作者：
KOMAREK, KL [1 ]
机构：
[1] UNIV VIENNA,INST ANORGAN CHEM,A-1010 VIENNA,AUSTRIA
来源：
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1977年 / 81卷 / 10期
关键词：
D O I：
10.1002/bbpc.19770811012
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Recent developments of experimental techniques for the measurement of thermodynamic quantities of liquid alloys are discussed with special emphasis on calorimetry, emf-measurements, and the Knudsen method. Selected experimental results of thermodynamic investigations are analyzed with respect to anomalies in the melts due to partial nonmetallic bonding. An interpretation of the anomalies is given in terms of formation of heteroatomic ″associates″ . Available data were checked to predict the occurrence of anomalies in binary melts.
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页码：936 / 950
页数：15
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