THE REACTIVITY OF OXYGEN NUCLEOPHILES WITH ARYL RADICALS IN THE S(RN)1 MECHANISM

被引：12

作者：

BAUMGARTNER, MT ^{[1
]}

PIERINI, AB ^{[1
]}

ROSSI, RA ^{[1
]}

机构：

[1] UNIV NACL CORDOBA,FAC CIENCIAS QUIM,DEPT QUIM ORGAN,SUC 16,RA-61 CORDOBA,ARGENTINA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)74201-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photostimulated reaction of 2-naphthoxide ions 1 with o-dihalobenzenes in liquid ammonia gives the halosubstituted product 4 and the cyclized substituted product 5. This is the first report about the coupling of an aromatic sigma-radical with an oxygen functionality in the chain propagation cycle of the S(RN)1 mechanism.

引用

页码：2323 / 2326

页数：4

共 17 条

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