GALLIUM COMPOUNDS WITH A 2-(N,N-DIMETHYLAMINO)ETHYLCYCLOPENTADIENYL LIGAND

被引：27

作者：

JUTZI, P

BANGEL, M

机构：

[1] Fakultät für Chemie der Universität Bielefeld, 33615 Bielefeld

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 480卷 / 1-2期

关键词：

GALLIUM; BRIDGING LIGANDS; CYCLOPENTADIENYL; MOCVD;

D O I：

10.1016/0022-328X(94)87135-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of cyclopentadienyl complexes containing the polydentate C5H4CH2CH2NMe2 ligand and the Group 13 element gallium is described. The compounds (C5H4CH2CH2NMe2)GaR2 (R = Br, Me, H) are obtained in good yields by salt elimination reactions. They show an additional intramolecular coordination of the nitrogen atom in the side chain. Monomeric structures, sufficient volatilities and well-behaved fragmentation make them potential candidates for MOCVD processes.

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页码：C18 / C19

页数：2

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