THE 1ST STRUCTURALLY CHARACTERIZED SODIUM PRIMARY AMIDE COMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE OF 2-PHOC6H4NHNA.NME[(CH2)2NME2]2

被引：12

作者：

CRAGGHINE, I ^{[1
]}

DAVIDSON, MG ^{[1
]}

EDWARDS, AJ ^{[1
]}

RAITHBY, PR ^{[1
]}

SNAITH, R ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 19期

关键词：

D O I：

10.1039/dt9940002901

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound 2-PhOC6H4NHNa.NMe[(CH2)2NMe2]2 has been synthesised by a 1: 1 reaction of sodium hydride with 2-phenoxyaniline in toluene in the presence of N,N,N',N',N'-pentamethyidlethylenetriamine (pmdien); X-ray crystallography revealed a solid-state structure comprising a near-symmetrical Na2N2 ring dimer with each sodium cation chelated by a tridentate pmdien ligand in an unprecedented near-planar conformation.

引用

页码：2901 / 2902

页数：2

共 13 条

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