MONOMETALLATION OF A DI(AMINOARYL) ETHER INDUCES A SMILES REARRANGEMENT LEADING TO A SODIUM ARYLOXIDE COMPLEX - THE SYNTHESIS AND CRYSTAL-STRUCTURE OF [(MEOCH2CH2)(C6H4NHCH2CH2OME)NC6H4O=NA]2

被引：11

作者：

CRAGGHINE, I

DAVIDSON, MG

KOCIAN, O

KOTTKE, T

MAIR, FS

SNAITH, R

STODDART, JF

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[3] INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 17期

关键词：

D O I：

10.1039/c39930001355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound was synthesised by 1 : 1 reaction of sodium hydride with a di(aminoaryl) ether ligand in toluene-hexamethylphosphoramide (HMPA) solution; X-ray crystallography revealed that an in situ Smiles rearrangement of the ligand had taken place to give a dimeric aryloxide sodium complex, which is in stark contrast to previous results obtained by 2 : 1 reaction of Bu(n)Li with the ligand in the absence of HMPA.

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页码：1355 / 1357

页数：3

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